Total Spontaneous Resolution of Five-Coordinate Complexes
✍ Scribed by Anders Lennartson; Mikael Håkansson
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 311 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Stereochemically labile copper and zinc complexes with the __N__,__N′__‐dimethylethylenediamine ligand (dmeda) have been shown to be promising precursors for the total spontaneous resolution of chiral covalent networks. (__N__,__N′__)‐[Cu(NO~3~)~2~(dmeda)]~∞~ crystallises as a conglomer
Various nonbond-rupture mechanisms have been described for the isonierizations of five-coordinate complexes [l]. Different representations of these processes have already been elaborated [l-51. In this note, we present some new formal properties of five-coordinate isomerizations which are closely re
The dichlorodihydridoruthenium (IV) compound [RuH 2 Cl 2 -were obtained. The phenylvinylidene complex [RuCl 2 (=C= CHPh)(PCy 3 ) 2 ] (15) was prepared from phenylacetylene and (PiPr 3 ) 2 ] (4) was prepared from [RuCl 2 (C 8 H 12 )] n (3), PiPr 3 , and H 2 in 2-butanol via the chlorohydridoruthenium