𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Group Theory and Stereoisomerism of Five-Coordinate Complexes

✍ Scribed by J. Brocas; M. Gielen

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
116 KB
Volume
80
Category
Article
ISSN
0037-9646

No coin nor oath required. For personal study only.

✦ Synopsis

Various nonbond-rupture mechanisms have been described for the isonierizations of five-coordinate complexes [l]. Different representations of these processes have already been elaborated [l-51. In this note, we present some new formal properties of five-coordinate isomerizations which are closely related to group theory.

The symmetry group D3h of the rigid molecule which is a trigonal bipyramid is of no interest in the study of stereoisomerism: it performs no chemistry. On the other

📜 SIMILAR VOLUMES

Synthesis and Molecular Structure of Six
Synthesis and Molecular Structure of Six-Coordinate Dichlorodihydridoruthenium(IV) and Five-Coordinate Vinylideneruthenium(II) Complexes
✍ Justin Wolf; Wolfram Stüer; Claus Grünwald; Olaf Gevert; Matthias Laubender; Hel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 284 KB 👁 2 views

The dichlorodihydridoruthenium (IV) compound [RuH 2 Cl 2 -were obtained. The phenylvinylidene complex [RuCl 2 (=C= CHPh)(PCy 3 ) 2 ] (15) was prepared from phenylacetylene and (PiPr 3 ) 2 ] (4) was prepared from [RuCl 2 (C 8 H 12 )] n (3), PiPr 3 , and H 2 in 2-butanol via the chlorohydridoruthenium

Five-Coordinate Carbides in Ti-Al-C Comp
Five-Coordinate Carbides in Ti-Al-C Complexes
✍ James E. Kickham; Frédéric Guérin; Jeffrey C. Stewart; Douglas W. Stephan 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB