Using translationally hot H atoms generated via the photolysis of HBr at 193 nm, we have investigated the dynamics of the reaction H + D20--,OD + H D at a center-of-mass energy of Ec.m. = 2.53 eV. The nascent OD (v= 0) rotational distribution was probed by laser-induced fluorescence. We found that o
Total reactive cross sections for the reaction H+D2=HD+D
β Scribed by Tsukiyama, K.; Katz, B.; Bersohn, R.
- Book ID
- 126268174
- Publisher
- American Institute of Physics
- Year
- 1986
- Tongue
- English
- Weight
- 366 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.450444
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Integral and differential state-resolved cross sections have been calculated by the method of quasiclassical trajectories for the H t D,+HD+D reaction in the range of initial conditions of interest to recent experiments. When possible, the results are compared to exact quantum-mechanical calculation
Using the laser photolysis vacuum-UV laser-induced fluorescence 'pump-and-probe' technique, Doppler profiles of H and D atoms from the reaction O(1D) + HD were measured under single-collision conditions, O(aD) atoms were generated by laser photolysis of N20 at 193 nm. With a calibration method using