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Total reactive cross sections for the reaction H+D2=HD+D

✍ Scribed by Tsukiyama, K.; Katz, B.; Bersohn, R.


Book ID
126268174
Publisher
American Institute of Physics
Year
1986
Tongue
English
Weight
366 KB
Volume
84
Category
Article
ISSN
0021-9606

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Absolute reactive cross section for the
✍ A. Jacobs; H.R. Volpp; J. Wolfrum πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 326 KB

Using translationally hot H atoms generated via the photolysis of HBr at 193 nm, we have investigated the dynamics of the reaction H + D20--,OD + H D at a center-of-mass energy of Ec.m. = 2.53 eV. The nascent OD (v= 0) rotational distribution was probed by laser-induced fluorescence. We found that o

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Integral and differential state-resolved cross sections have been calculated by the method of quasiclassical trajectories for the H t D,+HD+D reaction in the range of initial conditions of interest to recent experiments. When possible, the results are compared to exact quantum-mechanical calculation

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Absolute rate constants, reactive cross-
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