Differentialandtotal state-to-state~sssectionsfoortheD+H,(u=O,j=O-3)~HD(u',j')+Hreactioninthe0.35-1.10eV collision energy range, have been calculated on the UTH surface using the QCT method. The results are commented on and compared to recent quantum mechanical calculations and to experimental measu
State-resolved differential cross sections for the H+D2 (v=0, j) → HD(v′, j′)+D reaction from quasiclassical trajectory calculations
✍ Scribed by F.J. Aoiz; V.J. Herrero; O. Puentedura; V. Sáez Rábanos
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 567 KB
- Volume
- 198
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Integral and differential state-resolved cross sections have been calculated by the method of quasiclassical trajectories for the H t D,+HD+D reaction in the range of initial conditions of interest to recent experiments. When possible, the results are compared to exact quantum-mechanical calculations. The differential cross sections reported here should be useful for the evaluation of current molecular beam experiments on this reaction.
📜 SIMILAR VOLUMES
A close-coupling calculation of integral cross sections for the reaction F + Hz (u= 0, j= 0) +FH ( v'f ) + H has been performed in the threshold energy range using hyperspherical coordinates, The convergence of partial reaction probabilities with respect to a,, the maximum magnitude of the total ang
The reaction D+ H2( v= I ) has been investigated in a crossed molecular beam experiment at the most probable collision energy of&=0.33 eV. Angular and time-of-flight distributions have been measured and the total absolute cross section has been determined to be a&, = 0, v= 1, EC ,,,. = 0.33 eV) = 1.