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Total Optical Resolution of Free α-Amino-acids by the Inoculation Method

✍ Scribed by HARADA, KAORU


Book ID
109643369
Publisher
Nature Publishing Group
Year
1965
Tongue
English
Weight
216 KB
Volume
206
Category
Article
ISSN
0028-0836

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📜 SIMILAR VOLUMES


Optically pure α-amino acids by resoluti
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A new general method of resolution of &\_-amino acids via their Schiff bases with 2-hydroxy pinan-3-ones is described. It complements the asymmetric synthesis of o(-disubstituted amino acids by alkylation of the Schiff bases. Asymmetric synthesis methods1'2 seldom give enantiomerically pure amino a

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✍ Eishun Tsuchida; Hiroshi Nishikawa; Eiichi Terada 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 274 KB

The (N-benzyl-L-leucinato) copper(II) complex was shown pH titration to coordinate L-amino acids more strongly than D enantiomers. A chiral polymer complex, containing N-alkylated amino acid residue and copper(II) ion, was used partially to resolve some optically active amino acids. Unlike the (N-be