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Tosylhydrazide-Promoted Palladium-Catalyzed Reaction of β-Aminoketones with o-Dihaloarenes: Combining Organocatalysis and Transition-Metal Catalysis

✍ Scribed by Prof. José Barluenga; Noelia Quiñones; Dr. María-Paz Cabal; Prof. Fernando Aznar; Dr. Carlos Valdés

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 321 KB
Volume: 50
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201006996

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## Abstract Cross‐coupling of the tosylhydrazones, derived from Mannich adducts of cyclic ketones, with 1‐bromo‐2‐chlorobenzenes (II) is followed by an intramolecular C—N bond formation.