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ChemInform Abstract: Tosylhydrazide-Promoted Palladium-Catalyzed Reaction of β-Aminoketones with o-Dihaloarenes: Combining Organocatalysis and Transition-Metal Catalysis.

✍ Scribed by Jose Barluenga; Noelia Quinones; Maria-Paz Cabal; Fernando Aznar; Carlos Valdes

Publisher: John Wiley and Sons
Year: 2011
Weight: 50 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201125156

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✦ Synopsis

Abstract

Cross‐coupling of the tosylhydrazones, derived from Mannich adducts of cyclic ketones, with 1‐bromo‐2‐chlorobenzenes (II) is followed by an intramolecular C—N bond formation.

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