TOSS in high-speed MAS NMR
β Scribed by Niels Chr Nielsen; Henrik Bildsoe; Hans J Jakobsen
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 393 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0022-2364
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π SIMILAR VOLUMES
High-speed MAS gives a three-fold gain in resolution of the m++m -I ( m = 3/Z and -I /2) satellite transitions of I= 5/2 nuclei in polycrystalline samples compared with the conventional "central transition" spectroscopy. This is demonstrated using a standard high-field NMR spectrometer and samples o
The inverse cubic dependency of the acceleration of a rotor on its diameter allows for mechanical dynamics comparable to spin dynamics in coupled spin systems. Rotor acceleration up to 300 kHz/s was measured. This feature can be used to simplify existing experiments and explore entirely new ones in