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Torsional interactions in methyl vinyl ketone

✍ Scribed by A.C. Fantoni; W. Caminati; R. Meyer

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
515 KB
Volume
133
Category
Article
ISSN
0009-2614

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✦ Synopsis

Splittings between A and E sublevels in methyl vinyl ketone (arising from the internal rotation of the methyl group) in the ground and first excited states following methyl and skeletal torsions, and variations of the rotational constants with respect to the ground state, have been measured. A flexible model analysis of these and of previously available far infrared data yields information on the interaction between the two torsions, and partial information on structural relaxation.

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