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Methyl barrier to internal rotation and evidence of torsion-torsion interaction in methyl thiolcyanoformate

โœ Scribed by Walther Caminati


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
430 KB
Volume
90
Category
Article
ISSN
0022-2852

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Torsional symmetry dependence of S1 dyna
โœ David C. Moule; Richard H. Judge; Haisheng Liu; Edward C. Lim ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 391 KB ๐Ÿ‘ 2 views

The single-rovibronic-level fluorescence of ''intermediate-case'' molecules that undergo methyl internal rotation is strongly influenced by the torsional ลฝ . symmetry of the lowest excited singlet state S . The most dramatic example of such 1 symmetry dependence comes from our recent finding that th