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Torsion-vibration-rotation interaction in ethane: The bands ν12 + ν4, ν8 and ν6

✍ Scribed by Joel Susskind


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
710 KB
Volume
49
Category
Article
ISSN
0022-2852

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Effective Rotation–Vibration Parameters
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The jet-cooled spectrum of ethane in the region of the nu8 perpendicular fundamental vibration at 1472 cm-1 was recorded with a Fourier transform spectrometer at 0.01 cm-1 instrumental resolution. About 1150 lines were assigned to 18 subbands of nu8 ranging from K"DeltaK = -9 to +8. About 160 lines

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Torsional splittings of the C 2 H 6 hot band 9 ϩ 4 Ϫ 4 have been determined based on measurements taken with the Kitt Peak National Observatory Fourier transform spectrometer with .0025 cm Ϫ1 resolution. The measured splittings range from Ϫ.2347 cm Ϫ1 (the sign is relative to that of the observed sp

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High-resolution FTIR spectra of 1,1,1-trifluoroethane (HFC-143a) have been recorded in the region from 1370 to 1470 cm Ϫ1 with an unapodized resolution of 0.0016 cm Ϫ1 at room temperature and of 0.004 cm Ϫ1 at 183 and 100 K. The two main infrared active bands of A 1 symmetry have been shown to be 2