Topology Control of Porous Coordination Polymers by Building Block Symmetry

✍ Scribed by Ruslan A. Polunin; Sergey V. Kolotilov; Mikhail A. Kiskin; Olivier Cador; Elena A. Mikhalyova; Anton S. Lytvynenko; Stéphane Golhen; Lahcène Ouahab; Victor I. Ovcharenko; Igor L. Eremenko; Vladimir M. Novotortsev; Vitaly V. Pavlishchuk

• Publisher: John Wiley and Sons
• Year: 2010
• Tongue: English
• Weight: 362 KB
• Volume: 2010
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/ejic.201000929

✦ Synopsis

The coordination polymers [Fe 2 MO(piv) 6 (bipy) 1.5 ] n [M = Ni II , compound 1, and M = Co II , compound 2; piv = (CH 3 ) 3 CCO 2 and bipy = 4,4Ј-bipyridine] were prepared by linking trinuclear heterometallic pivalates, possessing D 3h symmetry, by linear molecules of bipy. The complexes are isostructural and are built from 2D doubly interpenetrated "honeycomb" layers. The structure of the starting polynuclear building blocks is retained, which opens the way for the creation of materials [a] L. V.