Dynamic Motion of Building Blocks in Porous Coordination Polymers
β Scribed by Satoshi Horike; Ryotaro Matsuda; Daisuke Tanaka; Seijiro Matsubara; Motohiro Mizuno; Kazunaka Endo; Susumu Kitagawa
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 478 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
The coordination polymers [Fe 2 MO(piv) 6 (bipy) 1.5 ] n [M = Ni II , compound 1, and M = Co II , compound 2; piv = (CH 3 ) 3 CCO 2 and bipy = 4,4Π-bipyridine] were prepared by linking trinuclear heterometallic pivalates, possessing D 3h symmetry, by linear molecules of bipy. The complexes are isost
## Abstract The use of the buildingβblock methodology in designing coordination framework materials are discussed, with particular reference to the structural reliability of a given building block. The term structural reliability is defined for a given metal containing moiety as the degree to which