To the theory of continuum resonance Raman scattering from diatomic molecules
β Scribed by V.V. Hizhnyakov; I.J. Tehver
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 314 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0030-4018
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## Abstract A theory is presented which describes resonance Raman scattering via continuum electronic states of diatomic molecules. It is applied to the dissociative continuum of the bounded __B__(^3^Ξ ~__o__+__u__~)βstate and the continuum of the repulsive ^1^Ξ ~1__u__~ state of the halogen molecule
A quantum-mechanical nonadiabatic theory of resonance Raman scattering via a system of many intersecting electronic terms is suggested. The radiative and nonradiative couplings are taken into account by the methods of high-order perturbation theory. The cases of weak and strong laser radiation are
The coupled equatiops of molecular collision theory can be formulated in such a way as to yield the amp!itude for resommce Roman scattering of li&t by ;L diatomic molecule. Tao vxknts of tke method can be adopted, characterized by different choices for the potential matrices. \_%li molecular potenti