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Titration of Elemental Sulfur with Solutions of Sodium Cyanide

✍ Scribed by Skoog, D. A.; Bartlett, J. K.


Book ID
126908392
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
393 KB
Volume
27
Category
Article
ISSN
0003-2700

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Elemental sulfur reacts with conjugated 1,3-dienes to deliver cyclic di-and polysulfides; the reaction proceeds without any activation other than heat. Treatment of cyclic polysulfide products with triphenylphosphine cleanly converts them to the corresponding disulfide in good overall yield. Additio