Photolysis of sodium cyanide in aqueous solution
β Scribed by K.-J. Hartig; N. Getoff
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 476 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0047-2670
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Flash photolysis of ethereal solutions of sodium results in the almost complete disappearance of the orfgind absorption b.and at 15000 cm-I and in the formation of solvated electrons. After the flash an intermediate with an absorption maximum at 12000 cm-l is formed. This absorption is assigned to a
Photolysis of pyrophosphate and tripolyphosphate ions in aqueous solution is proposed to produce electron detachment with formation of pyrophosphate and tripolyphosphate radicals (with quantum yields Ο½0.1 at 266 nm), respectively. Formation of P 2 O 7 ΠΈ 3Οͺ is observed after photolysis of both polyph