Titan's 5 μm Spectral Window: Carbon Monoxide and the Albedo of the Surface
✍ Scribed by Keith S. Noll; Thomas R. Geballe; Roger F. Knacke; Yvonne J. Pendleton
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 228 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0019-1035
No coin nor oath required. For personal study only.
✦ Synopsis
We have measured the spectrum of Titan near 5 micrometers and have found it to be dominated by absorption from the carbon monoxide 1-0 vibration-rotation band. The position of the band edge allows us to constrain the abundance of CO in the atmosphere and/or the location of the reflecting layer in the atmosphere. In the most likely case, 5 micrometers radiation is reflected from the surface and the mole fraction of CO in the atmosphere is qCO=10(+10/-5) ppm, significantly lower than previous estimates for tropospheric CO. The albedo of the reflecting layer is approximately 0.07(+0.02/-0.01) in the 5 micrometers continuum outside the CO band. The 5 micrometers albedo is consistent with a surface of mixed ice and silicates similar to the icy Galilean satellites. Organic solids formed in simulated Titan conditions can also produce similar albedos at 5 micrometers.
📜 SIMILAR VOLUMES
Platinum(0)-Catalyzed Carbonylative Lactonization of 5-Hydroxy-1pentyne with Carbon Monoxide in the Presence of Thiols. -The cyclocarbonylation of title compound (I) to give α-methylene-δ-lactone (III) is found to proceed efficiently by using catalytic Pt(PPh 3 ) 4 in the presence of small amounts
tert-Butyl isocyanide reacts with the m 3 -alkylidyne complex [{TiCp\*(m-O)} 3 (m 3 -CH)] (1, Cp\* h 5 -C 5 Me 5 ) to give a single insertion into a m 3 -carbon ± titanium bond and the formation of the new derivative [{TiCp\* (m-O)} 3 (m 3 -h 2 -HCCNtBu)] (3). Similar reactions of 2,6-Me 2 C 6 H 3 N