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Titanium-salan-catalyzed asymmetric sulfoxidations with H 2 O 2 : design of more versatile catalysts

✍ Scribed by Talsi, Evgenii P.; Bryliakov, Konstantin P.


Book ID
120344672
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
320 KB
Volume
27
Category
Article
ISSN
0268-2605

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Asymmetric oxidation of sulfides with H2
✍ Konstantin P. Bryliakov; Evgenii P. Talsi πŸ“‚ Article πŸ“… 2007 πŸ› Elsevier Science 🌐 English βš– 551 KB

Sulfoxidation catalysts generated in situ from titanium(IV) isopropoxide and enantiopure Schiff bases promote the enantioselective oxidation of alkyl aryl sulfides to the corresponding sulfoxides at low catalyst loadings (<1 mol%), 30% aqueous hydrogen peroxide being the terminal oxidant. Upon scree