✦ LIBER ✦

Titanium-mediated synthesis of bicyclic cyclopropylamines from unsaturated nitriles

✍ Scribed by Christophe Laroche; Philippe Bertus; Jan Szymoniak

Book ID: 104253212
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 103 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00325-3

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✦ Synopsis

Here we report an easy synthesis of bicyclic primary cyclopropylamines directly from unsaturated nitriles. The described reaction involves Ti(II)-mediated intramolecular coupling of alkene and nitrile moieties.

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