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Titanium and Zirconium Et 2 C 2 B 4 H 4 −Metal−Phosphine Complexes: Synthesis, Characterization, and Ethylene Polymerization Activity 1

✍ Scribed by Dodge, Tye; Curtis, Michael A.; Russell, J. Monte; Sabat, Michal; Finn, M. G.; Grimes, Russell N.


Book ID
126177133
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
120 KB
Volume
122
Category
Article
ISSN
0002-7863

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Synthesis and characterization of titani
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6, are described. 1 was obtained from the reaction of TiCl 4 and Me 3 SiN C t Bu 2 and used as starting material for the preparation of 2 and 3. Complex 4 was obtained by reaction of 2 with PhCH 2 MgCl. Complexes 5 and 6 were prepared by addition of B(C 6 F 5 ) 3 to 3 and 4, respectively. The NMR sp