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Synthesis and structural characterization of a bis(cyclopentadienyl)methane-cobaltacarborane complex: CH2[closo-1-(.eta.-C5H4)Co(2,3-Et2C2B4H4)]2

✍ Scribed by Plumb, Carole A.; Carroll, Patrick J.; Sneddon, Larry G.


Book ID
127025575
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
414 KB
Volume
30
Category
Article
ISSN
0020-1669

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## Abstract The cobaltocenium salts [Co{C~5~H~4~(B__i__Pr~2~)}~2~]PF~6~ [(1a)PF~6~] and [Co{C~5~H~4~(BMe~2~)}~2~]PF~6~ [(1b)PF~6~] are strong Lewis acids. With pyridine (1a)PF~6~ forms a mono‐adduct 2 and a di‐adduct 3 which show NMR spectra in the low‐temperature regime of pyridine exchange. With