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Tin-Free and Catalytic Radical Cyclizations

✍ Scribed by Smith, Deborah M.; Pulling, Mary E.; Norton, Jack R.

Book ID
127162035
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
59 KB
Volume
129
Category
Article
ISSN
0002-7863

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A set of allene-tethered benzoyloximes (5) has been treated N atom to give the dihydropyridines 8. If the stannyl radical adds on the benzoyl moiety, an iminyl radical is formed with nBu 3 SnH. Depending on their substitution pattern, a wide range of compounds has been obtained. If the stannyl whic