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Tin-Free and Catalytic Radical Cyclizations.

✍ Scribed by Deborah M. Smith; Mary E. Pulling; Jack R. Norton


Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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Tin-Mediated Free-Radical Cyclization of
✍ MichaΓ«l Depature; Josef Diewok; Jacques Grimaldi; Jacques Hatem πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 329 KB πŸ‘ 1 views

A set of allene-tethered benzoyloximes (5) has been treated N atom to give the dihydropyridines 8. If the stannyl radical adds on the benzoyl moiety, an iminyl radical is formed with nBu 3 SnH. Depending on their substitution pattern, a wide range of compounds has been obtained. If the stannyl whic