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Tin-containing nasicon-related compounds: A new mixed valence compound, Sn0.5Sn2P3O12, containing Sn4+ and Sn2+ and lithium incorporation within CuSn2P3O12

✍ Scribed by Frank J. Berry; Robert C. Thied


Book ID
117623870
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
284 KB
Volume
257
Category
Article
ISSN
0925-8388

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Tin-Containing Nasicon-Related Compounds: A New Mixed Valence Compound, Sn0.5Sn2P3O12, Containing Sn4+ and Sn2+ and Lithium Incorporation within CuSn2P3O12. -The novel mixed valence tin compound Sn0.5Sn2P3O12 is prepared by sequential heating of a stoichiometric mixture of SnO and SnO2 to 1000 β€’ C.

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A new tin(II) phosphate, [NH 3 CH 2 CH(NH 3 )CH 3 ] 0.5 [Sn 4 P 3 O 12 ] ' H 2 O, was synthesized by hydrothermal technique. It crystallizes in monoclinic space group P2 1 /c (No. 14) with lattice parameters a ‫؍‬ 7.326(1) A s , b ‫؍‬ 23.614(3) A s , c ‫؍‬ 9.081(1) A s , ‫؍‬ 102.8(1)3, V ‫؍‬ 1532.1(