✦ LIBER ✦

Synthesis and Structure of a New Open-Framework Tin(II) Phosphate, [NH3CH2CH(NH3)CH3]0.5[Sn4P3O12]·H2O, Possessing One-Dimensional Channels

✍ Scribed by Srinivasan Natarajan

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 393 KB
Volume: 148
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.1999.8343

No coin nor oath required. For personal study only.

✦ Synopsis

A new tin(II) phosphate, [NH 3 CH 2 CH(NH 3 )CH 3 ] 0.5 [Sn 4 P 3 O 12 ] ' H 2 O, was synthesized by hydrothermal technique. It crystallizes in monoclinic space group P2 1 /c (No. 14) with lattice parameters a ‫؍‬ 7.326(1) A s , b ‫؍‬ 23.614(3) A s , c ‫؍‬ 9.081(1) A s , ‫؍‬ 102.8(1)3, V ‫؍‬ 1532.1(1) A s 3 , Z ‫؍‬ 3, R ‫؍‬ 4.3%.

The structure consists of one-dimensional channels, constituting a network of strictly alternating SnO 3 and PO 4 moieties connected through vertices. The structure-directing amine molecule 1,2-diaminopropane occupies the channels along with water molecules.

📜 SIMILAR VOLUMES

[H3N(CH2)2NH3][Sn4P3O12]−: An Open-Frame

[H3N(CH2)2NH3][Sn4P3O12]−: An Open-Framework Tin(II) Phosphate

✍ Dr. Srinivasan Natarajan; Dr. Martin P. Attfield; Prof. Anthony K. Cheetham 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 372 KB 👁 1 views

enforce an increase in the charge separation. However, whether an 0x0 ligand is sufficiently voluminous to have this steric effect is debatable, and calculations are currently underway to resolve this question." ' 1 Although the greater thermodynamic stability of the trans alcohol with respect to th

ChemInform Abstract: Synthesis and Struc

ChemInform Abstract: Synthesis and Structure of an Open-Framework Tin Phosphate, (H3N(CH2) 4NH3)2+0.5(Sn4P3O12)-, Containing Intersecting Channels.

✍ S. NATARAJAN; A. K. CHEETHAM 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

A Nickel Molybdenum Phosphate with Tunne

A Nickel Molybdenum Phosphate with Tunnel: Hydrothermal Synthesis and Structure of (NH3CH2CH2NH3)4 · (NH3CH2CH2NH2) · Na · [Ni2Mo12O30(PO4)(HPO4)4(H2PO4)3] · 6H2O

✍ Lin Xu; Yaqiu Sun; Enbo Wang; Enhong Shen; Zhongri Liu; Changwen Hu; Yan Xing; Y 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 158 KB

A nickel molybdenum phosphate, (NH 3 CH 2 CH 2 NH 3 ) 4 ' (NH 3 CH 2 CH 2 NH 2 ) ' Na ' [Ni 2 Mo 12 O 30 (PO 4 ) (HPO 4 ) 4 (H 2 PO 4 ) 3 ] ' 6H 2 O, involving molybdenum present in V oxidation, has been hydrothermally synthesized and structurally characterized by single crystal X-ray di4raction. De

Synthesis and Characterization of a New

Synthesis and Characterization of a New Layered Aluminophosphate [Al3P4O16][(CH3)2NHCH2CH2NH(CH3)2][H3O]

✍ Wenfu Yan; Jihong Yu; Yi Li; Zhan Shi; Ruren Xu 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 248 KB

Synthesis and Structure of the First Thr

Synthesis and Structure of the First Three-Legged Low-Dimensional Iron Phosphate, [H3N(CH2)3NH2 (CH2)2NH2 (CH2)3NH3] [Fe3F6(HPO4)2(PO4)] ×3H2O.

✍ Sukhendu Mandal; Swapan K. Pati; Mark A. Green; Sue-Lein Wang; Srinivasan Natara 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 62 KB 👁 3 views

ChemInform Abstract: Synthesis of a Laye

ChemInform Abstract: Synthesis of a Layered Zinc Phosphate, [NH3(CH2)2NH2 (CH2)3NH3] [Zn2(PO4)(HPO4)2] ×H2O, and Its Transformation to an Extra-Large Pore Three-Dimensional Zinc Phosphate, [NH3(CH2)2NH2 (CH2)3NH3] [Zn3(PO4)(HPO4)3].

✍ Srinivasan Natarajan 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views