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Tin-119 Mössbauer investigations of mixed oxide catalysts

✍ Scribed by Frank J. Berry

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
265 KB
Volume
39
Category
Article
ISSN
0020-1693

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✦ Synopsis

Tin-119 Miissbuuer spectra show that the cationic oxidation states and crystal structures of some mived oxide catalysts remain unaltered by the adsorption of acidic or basic molecules. Reaction of the oxides with either hydrogen or butenes gives reduced catalysts in which the retention of the tin atom with an oxidation state of (IV) is accompanied by an attenuation of the electric field gradient at the tin nuclei. The results are related to the catalytic properties of these materials.

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