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Tin-119 Mössbauer and ESR investigations of the tin--antimony oxide system

✍ Scribed by Frank J. Berry; Alfred G. Maddock

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
210 KB
Volume
31
Category
Article
ISSN
0020-1693

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✦ Synopsis

Tin-antimony oxides of the type SnJb,O2 (x = 0.01-0.10) when calcined at 873K form solid solutions in which the Miissbauer parameters steadily depart from those of stannic oxide but provide no evidence for the formation of localised tin(U). Esr measurements indicate the presence of a spin free surface species. Above x = 0.10 a two phase region exists in which the tin rich phase shows constant "'Sn Miissbauer parameters.

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