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Time resolved observations of NH2 and benzyl radicals produced in the infrared multiple photon dissociation of benzylamine

✍ Scribed by H. Reisler; F.B.T. Pessine; C. Wittig

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 496 KB
Volume: 99
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80160-2

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✦ Synopsis

T11c average internal energy of benzylamine molecules dissociated via infrared multiple photon excitation is derived from laser induced fluorcsccnce (LIF] measurements of [Nf-12] versus time, and is SO-70 kcal mol-' above threshold at fluences of IO-30 J cm-Z_ Ihc benzyl radical is monitored by LIF and is produced vibrationally "hot*'_ f;luorescence lifet-mzes af bands in its 1 2.\2 -1 zB2 system are reponcd.

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