✦ LIBER ✦

Real-time observation of :CF2 formation in the infrared multiple-photon dissociation of fluoroform-d

✍ Scribed by S.K. Sarkar; D.K. Palit; K.V.S.Rama Rao; J.P. Mittal

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 622 KB
Volume: 131
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)87155-x

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✦ Synopsis

I986 :CFz radicals are directly detected by transient absorption at 249 nm in the TEA CO, laser-induced decomposition of CDF,. Vlbrationally hot :CFz radicals, T,z 725 K, are produced in a 4-5 ps time scale. Second-order decay of :CFz radicals is also observed, yielding the dimerisation rate constant Kz = 4.2 x 10' M --' s-'.

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