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Time-resolved laser-induced fluorescence of the iodine B3π(0u+) state: Study of the second maximum of predissociation

✍ Scribed by F. Castaño; E. Martínez; M.T. Martínez

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
344 KB
Volume
128
Category
Article
ISSN
0009-2614

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✦ Synopsis

Fluorescence decay lifetimes for specific rovibrational levels of the Iz B 311(0: ) state, have been obtained by time-resolved laser-induced fluorescence. Gyroscopic and hyperfine predissociation parameters C,' and a,,, * for vibrational levels of the B311(O: ) state around the second maximum of predissociation, v'= 24, 25, have been determined. Results are discussed in terms of the dependence of the predissociation paramaters on the Franck-Condon densities and the correspdnding electronic matrix elements.

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