✦ LIBER ✦

Time-resolved Fourier transform infrared study of the 193 nm photolysis of SO2

✍ Scribed by Yuchuan Gong; Vladimir I. Makarov; Brad R. Weiner

Book ID: 104108439
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 250 KB
Volume: 378
Category: Article
ISSN: 0009-2614
DOI: 10.1016/s0009-2614(03)01180-1

No coin nor oath required. For personal study only.

✦ Synopsis

The 193 nm photolysis of SO 2 has been studied by monitoring the infrared emission of the vibrationally excited species using time-resolved FTIR emission spectroscopy. Evidence for a direct electronic transition from the e C C state to the ground state of SO 2 was found in addition to photodissociation following the 193 nm excitation. Relaxation rate constants for the observed vibrationally excited species, SO, SO 2 (m 1 ), and SO 2 (m 3 ), were calculated from the experimental decays.

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