✦ LIBER ✦
Time-resolved FTIR photofragment emission spectroscopy: HCl vibrational distributions from the 193 nm photolysis of chloroethylenes
✍ Scribed by D.J. Donaldson; Stephen R. Leone
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 602 KB
- Volume
- 132
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
With minor modifications
to commercial instrumentation, time-resolved FTIR emission spectroscopy is demonstrated for the determination of photofragment internal state distributions.
Vinyl chloride and dichloroethylene photolysis at 193 nm serve as test cases and exhibit high signal-to-noise.
The vibrational distributions in the first four levels of the HCl photoproduct of vinyl chloride and 1,2-transdichloroethylene are in good agreement with previous determinations.