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Time-resolved fluorescence spectra of s-tetracyanobenzene-toluene complex

โœ Scribed by K. Egawa; N. Nakashima; N. Mataga; Ch. Yamanaka

Book ID
103009123
Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
269 KB
Volume
8
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Time-resolved CT(charge transfer) fluorescence spectra and the fluorescence rise and decay curves at various wavelengths of the CT fluorescence band have been measured for the stetracyanobenzene (TCNB)-toluene system at various temperatures. The measurements have demonstrated clearly the relaxation process including the surroundfng solvent molecuies from the Franck-Condon state to the equilibrium state of the complex, resulting in the extraordinary large Stokes shift of the CT fluorescence.

๐Ÿ“œ SIMILAR VOLUMES

Fluorescence spectra and excited singlet
Fluorescence spectra and excited singlet-singlet absorption spectra of s-tetracyanobenzene EDA complexes by laser excitation
โœ H. Masuhara; N. Mataga ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 290 KB

The excited singlet-singlet absorption spectra of s-tetracyaobenzene (TCNB) complexes with toluene and benzene were observed. The spectra were obtnined using the re-absorption of the CT fluorescence by the fluorescent EDA complexes produced densely by means of the excitation with a giant pulse Iaser