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Time-Dependent Raman Analysis of Metal-to-Ligand Charge Transfer Excited States: Application to Radiative and NonRadiative Decay

โœ Scribed by Thompson, Darla Graff; Schoonover, Jon R.; Timpson, Cliff J.; Meyer, Thomas J.


Book ID
127007099
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
157 KB
Volume
107
Category
Article
ISSN
1089-5639

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โœ L.K. Orman; J.B. Hopkins ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 352 KB

Picosecond resonance Raman has been employed in a two-color pump/probe experiment to re-evaluate the assignments of metal to ligand charge transfer ground and excited state bands in tris-2,2'-bipyridine Ru(II). It is shown that there is no spectral overlap between ground and excited state bands and