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Tilt/Asymmetry in Nitrosyl Metalloporphyrin Complexes: The Cobalt Case

✍ Scribed by Ellison, Mary K.; Scheidt, W. Robert


Book ID
127253049
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
35 KB
Volume
37
Category
Article
ISSN
0020-1669

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Mechanism of chiral asymmetry generation
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Chiral asymmetry generation, the predominant production of one enantiomer in a non-chiral environment, could occur in the production of the chiral complex cis-[CoBr(NH 3 )(en) 2 ]Br 2 by the reaction of [Co(H 2 O) 2 {(OH) 2 Co(en) 2 } 2 ](SO 4 ) 2 with ammonium bromide in an aqueous medium. The main