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A Theoretical Study of Axial Tilting and Equatorial Asymmetry in Metalloporphyrin−Nitrosyl Complexes

✍ Scribed by Ghosh, Abhik; Wondimagegn, Tebikie


Book ID
120708409
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
102 KB
Volume
122
Category
Article
ISSN
0002-7863

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## Abstract In four series of strictly related organocobalt complexes, derived from cobaloximes by replacement of the O…H…O with O…‐BF~2~…O and/or (CH~2~)~3~ groups, the trends of ^59^Co‐NMR shielding and electrochemical data are discussed. A largely parallel behaviour of the plots of E~1/2~(I) val