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TiIV-BINOLate-Catalyzed Highly Enantioselective Additions of β-Substituted Allylstannanes to Aldehydes

✍ Scribed by Dipl.-Chem. Stefan Weigand; Prof. Dr. Reinhard Brückner

Book ID: 102793079
Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 940 KB
Volume: 2
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.19960020907

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The enantioselective addition of diethylzinc to aldehydes was conveniently achieved by using a catalyst prepared in situ by mixing titanium tetraisopropoxide with Sor R-binaphthol. Optical yields as high as 95.6% were obtained, t~) 1997 Elsevier Science Ltd. All rights reserved.