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BINOL-Catalyzed Highly Enantioselective Terminal Alkyne Additions to Aromatic Aldehydes

✍ Scribed by Moore, David; Pu, Lin


Book ID
125943061
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
44 KB
Volume
4
Category
Article
ISSN
1523-7060

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Enantioselective addition of diethylzinc
✍ Fu-Yao Zhang; Chiu-Wing Yip; Rong Cao; Albert S.C. Chan πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 266 KB

The enantioselective addition of diethylzinc to aldehydes was conveniently achieved by using a catalyst prepared in situ by mixing titanium tetraisopropoxide with Sor R-binaphthol. Optical yields as high as 95.6% were obtained, t~) 1997 Elsevier Science Ltd. All rights reserved.