Threshold kinetic processes for t-C4F9I
โ Scribed by Ja H. Lee; John W. Wilson; Therese Enderson; Donald H. Humes; Willard R. Weaver; Bagher M. Tabibi
- Book ID
- 103314356
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 219 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0030-4018
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## Abstract The rate of the reverse reaction of the system equation image has been measured in the range of 584โ604 K from a study of the azomethane sensitized pyrolysis of isobutane. Assuming the published value for the rate constant of recombination of __t__โbutyl we obtain Combination with o
The metathesis reaction of DI with t X4H9 generated by 351-nm photolysis of 2,2'-azoisopropane was studied in a low-pressure reactor (VLP@ Knudsen cell) in the temperature range of 302-411 K. The data obeyed the following Arrhenius relation when combined with recent data by Rossi and Golden gathered
The Arrhenius parameters for the title reaction have been measured in a very-low-pressure pyrolysis apparatus in the temperature range 644-722 K and are given by log kZ (A4-I. sec-I) = 9.68 -2.12/8, where 0 = 2.303RT in kcal/mol. Together with the published Arrhenius parameters for the reverse react