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Three New Structural Types of Mo/Ag/S Polymeric Complexes

✍ Scribed by Heng Yu; Wenjian Zhang; Xintao Wu; Tianlu Sheng; Quanming Wang; Ping Lin

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
92 KB
Volume
37
Category
Article
ISSN
0044-8249

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✦ Synopsis

Wavelike, zigzag, and helical polymers are formed by the reaction of [MoS ] , Ag S, and a complementary cation. The framework of the polymeric anions depends on the valence state of the latter. For example, the butterfly-type anionic chain shown in the picture is formed upon use of a divalent cation. There is a general tendency that a higher valence state of the cation will induce a more compact chain structure.

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