Structural Properties and Topological Diversity of Polymeric Ag(I)-hexamethylenetetramine Complexes: Self-Assembly of Three Novel Two-Dimensional Coordination Networks and Their Supramolecular Interactions

✍ Scribed by Lucia Carlucci; Gianfranco Ciani; Davide M. Proserpio; Silvia Rizzato

• Publisher: Elsevier Science
• Year: 2000
• Tongue: English
• Weight: 304 KB
• Volume: 152
• Category: Article
• ISSN: 0022-4596
• DOI: 10.1006/jssc.2000.8684

✦ Synopsis

The self-assembly of polymeric open networks from di4erent Ag(I) salts and the potentially tetradentate ligand hexamethylenetetramine (hmt) has revealed a variety of possible structural motifs, depending on the reagent ratios and the counterions, that are discussed in comparison. Three new Ag(I) coordination polymers are here described, namely 3), that contain twodimensional in5nite layers of di4erent types.