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Three New Neolignans from the Aril of Myristica fragrans

✍ Scribed by Fei Li; Xiu-Wei Yang


Publisher
John Wiley and Sons
Year
2007
Tongue
German
Weight
71 KB
Volume
90
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Three new neolignans, named 1‐deoxycarinatone (1), isodihydrocarinatidin (2), and isolicarin A (3), together with the known neolignan (+)‐dehydrodiisoeugenol (4), were isolated from mace (the aril of Myristica fragrans Houtt.). Their structures were elucidated as 2‐[(1__S__)‐2‐(4‐hydroxy‐3‐methoxyphenyl)‐1‐methylethyl]‐6‐methoxy‐4‐(prop‐2‐enyl)phenol (1), 4‐[(2__R__,3__R__)‐2,3‐dihydro‐7‐methoxy‐3‐methyl‐5‐(prop‐2‐enyl)benzofuran‐2‐yl]‐2‐methoxyphenol (2), and 4‐{(2__S__,3__R__)‐2,3‐dihydro‐7‐methoxy‐3‐methyl‐5‐[(1__E__)‐prop‐1‐enyl]benzofuran‐2‐yl}‐2‐methoxyphenol (3) on the basis of spectroscopic data.


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