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Three-dimensional bis(m-phenylene)-32-crown-10-based cryptand/paraquat catenanes

✍ Scribed by Liu, Ming; Li, Shijun; Zhang, Mingming; Zhou, Qizhong; Wang, Feng; Hu, Menglong; Fronczek, Frank R.; Li, Ning; Huang, Feihe


Book ID
118266533
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
353 KB
Volume
7
Category
Article
ISSN
1477-0520

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## Abstract The successful preparation of the first bis(__m__‐phenylene)‐32‐crown‐10/paraquat [2]rotaxane showed unambiguously that psuedorotaxane‐type complexation, rather than the taco‐complex‐type complexation previously observed in the solid state and in solution, exists – in solution – for com

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A bis(m-phenylene)-32-crown-10-based host to which are covalently attached two pyrene groups as fluorescence chromophores was designed and synthesized. Its complexations with paraquat (PQ) and diquat (DQ) were studied by proton NMR, ESI mass spectrometry, and UV-vis spectroscopy. Its chemosensor beh