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A Bis(m-phenylene)-32-crown-10/Paraquat [2]Rotaxane

✍ Scribed by Shijun Li; Kelong Zhu; Bo Zheng; Xianhong Wen; Ning Li; Feihe Huang


Book ID
102177019
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
299 KB
Volume
2009
Category
Article
ISSN
1434-193X

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✦ Synopsis


Abstract

The successful preparation of the first bis(m‐phenylene)‐32‐crown‐10/paraquat [2]rotaxane showed unambiguously that psuedorotaxane‐type complexation, rather than the taco‐complex‐type complexation previously observed in the solid state and in solution, exists – in solution – for complexation between bis(m‐phenylene)‐32‐crown‐10 derivatives and paraquat derivatives.(Β© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)


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A bis(m-phenylene)-32-crown-10-based host to which are covalently attached two pyrene groups as fluorescence chromophores was designed and synthesized. Its complexations with paraquat (PQ) and diquat (DQ) were studied by proton NMR, ESI mass spectrometry, and UV-vis spectroscopy. Its chemosensor beh