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Three-dimensional arrays of Si clusters grown at water surfaces and Si (100) surfaces

✍ Scribed by S. Sato; N. Yamamoto; K. Nakanishi; H. Yao; K. Kimura


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
312 KB
Volume
66
Category
Article
ISSN
0167-9317

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✦ Synopsis


Micrometer-sized three-dimensional Si cluster arrays have been synthesized at an air-water interface and a water-hydrogen-terminated Si (100) interface leveraging the hydrophobic nature of Si clusters. Structures of the arrays grown at these two different interfaces are compared. The array packing structures adopt either a b.c.c. structure with a 5 0.69 nm or an f.c.c. structure with a 5 0.75 nm at an air-water interface. Those grown on the Si substrate form two types of b.c.c. structures with a 5 0.61 and 0.69 nm. The distance between centers of adjacent Si clusters is 5.3 nm in both the b.c.c. structure with a 5 0.61 nm and the f.c.c. structure with a 5 0.75 nm. It is concluded that component clusters in the arrays grown at both types of interfaces are identical.


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