We have performed density functional calculations using cluster models of the C(100), Si(100) and Ge(100) surfaces. We find that the ground-state geometry is strongly dependent upon the constraints imposed during geometry optimization and also can be affected significantly by the cluster size in the
Three-dimensional arrays of Si clusters grown at water surfaces and Si (100) surfaces
β Scribed by S. Sato; N. Yamamoto; K. Nakanishi; H. Yao; K. Kimura
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 312 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0167-9317
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β¦ Synopsis
Micrometer-sized three-dimensional Si cluster arrays have been synthesized at an air-water interface and a water-hydrogen-terminated Si (100) interface leveraging the hydrophobic nature of Si clusters. Structures of the arrays grown at these two different interfaces are compared. The array packing structures adopt either a b.c.c. structure with a 5 0.69 nm or an f.c.c. structure with a 5 0.75 nm at an air-water interface. Those grown on the Si substrate form two types of b.c.c. structures with a 5 0.61 and 0.69 nm. The distance between centers of adjacent Si clusters is 5.3 nm in both the b.c.c. structure with a 5 0.61 nm and the f.c.c. structure with a 5 0.75 nm. It is concluded that component clusters in the arrays grown at both types of interfaces are identical.
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