Three Cyclized Isoprenylated Flavonoids from the Roots and Rhizomes of Sophora tonkinensis
✍ Scribed by Peilan Ding; Daofeng Chen
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- German
- Weight
- 227 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
Two new flavanones, tonkinochromanes D (1) and E (2), and a new chalcone, tonkinochromane F (3), were isolated from the roots and rhizomes of Sophora tonkinensis. Their structures were elucidated by spectroscopic methods, including 2D‐NMR and circular‐dichroism (CD) techniques, in combination with HR‐MS analysis. Compounds 1–3, as well the previously reported tonkinochromanes A–C, were shown by LC‐MS analysis to be ‘artifacts’ resulting from acid‐catalyzed electrophilic cyclization of isoprenyl side chains during extraction.
📜 SIMILAR VOLUMES
## Abstract Three new flavonoids, which are isoprenylated by fused 2,2‐dimethyl‐3,4‐dihydro‐2__H__‐pyran moieties, were isolated from the roots of __Sophora flavescens__ and named flavenochromanes A–C (**1**–**3**). Their structures were elucidated by spectroscopic methods, including 2D‐NMR techniq