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Thiosugars. II. Rearrangement of 2-(3,4,6-Tri-O-acetyl-2-amino-2-deoxy-β-D-glucopyranosyl)-2-thiop seudourea 1a,b

✍ Scribed by Wolfrom, M. L.; Horton, D.; Hutson, D. H.


Book ID
120003397
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
426 KB
Volume
28
Category
Article
ISSN
0022-3263

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Methyl 3,4,6-tri-O-acetyl-2-de­oxy-2-azi
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The title compound, C 51 H 56 N 4 O 21 Á0.1C 6 H 14 , crystallizes with two independent protected trisaccharide molecules and a partially occupied hexane solvent molecule in the asymmetric unit. The major conformational difference between the two trisaccharide molecules involves the O-acetyl group a