Thiophenol-Promoted Radical Cyclization of Hydrazones and Oxime Ethers. -Ethylenic and acetylenic tethered hydrazones or oxime ethers undergo a thiophenol radical induced cyclization providing a number of carbaor heterocyclic products.
โฆ LIBER โฆ
Thiophenol promoted radical cyclisation of hydrazones and oxime ethers
โ Scribed by Laurent El Kaim; Ariane Gacon; Aymeric Perroux
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 173 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Thiophenol radical induced cyclisation of N-dimethyltriazolyl imines is reported. Ethylenic but also acetylenic tethered hydrazones are cyclisud to cycloalkyl hydrazine under smooth conditions. A comparative study with oxime ethers is described.
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