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Thiocyanates and Isothiocyanates. III. 1 Kinetics and Mechanism of Benzhydryl Thiocyanates Isomerization

✍ Scribed by Iliceto, Antonio; Fava, Antonino; Mazzucato, Ugo; Rossetto, Olinda

Book ID
118005746
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
773 KB
Volume
83
Category
Article
ISSN
0002-7863

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THIOCYANIC acid esters have long been known to undergo thermal isomerization to give the corresponding isothiocyanic acid esters. Although the isomerization reaction is believed to be quite general and is frequently used as a synthetic route to isothiocyanates, little is known about its nature and m

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The mechanism of isomerization of allyl thiocyanate to allyl isothiocyanate has been investigated both experimentally and theoretically. The kinetic study indicates that the reaction is unimolecular and is not ionic. The entropy of activation suggests strongly that the mechanism involves a cyclic tr