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Kinetics and Mechanism of a Double Thiocyanate-Isothiocyanate Isomerization: A Round Robin Rearrangement

โœ Scribed by Emerson, David W.; Titus, Richard L.; Steinberg, Spencer M.; Jones, Marlon D.

Book ID
118005764
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
235 KB
Volume
59
Category
Article
ISSN
0022-3263

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Thiocyanates and isothiocyanates. Equili
Thiocyanates and isothiocyanates. Equilibrium, kinetics and mechanisms of isomerization
โœ A. Iliceto; A. Fava; U. Mazzucato ๐Ÿ“‚ Article ๐Ÿ“… 1960 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 382 KB

THIOCYANIC acid esters have long been known to undergo thermal isomerization to give the corresponding isothiocyanic acid esters. Although the isomerization reaction is believed to be quite general and is frequently used as a synthetic route to isothiocyanates, little is known about its nature and m